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"Gossip Girl" star Leighton Meester performed for the crowd at the American Eagle Outfitters Flagship Store opening party in Times Square on Tuesday.

Leighton Meester at the American Eagle Outfitters Flagship Store opening party

See Leighton, Ashlee Simpson, Adrian Grenier and more celebs at the party

At the event, Meester told MTV News she has been collaborating with Lil Wayne for her upcoming album. "I met [Wayne] a few months ago, and he's honestly... I don't even know if he'll want people to know that he's incredibly polite and respectful."

The actress and rapper teamed up for the track "Make It Rain." Meester added, "He's so talented and very funny. And really optimistic, and super supportive of me, which I've really, really appreciated so much."

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