Aaron Eckhart and Jennifer Aniston fall for each other on-screen in the romantic comedy "Love Happens" -- and Aaron tells "Extra" the chemistry comes from not hooking up!

jennifer aniston love happens

At the film's L.A. premiere, the handsome actor explained why they had such great chemistry. "We did. It's because we didn't sleep together. I think that's the key to a longer and lasting relationship."

Aniston also had love on her mind at the premiere. The star, wearing a beautiful silver Valentino mini, told "Extra" she believes in love at first sight -- but that love also has the potential to grow. "I think both are absolutely possible," she dished.

Jennifer Aniston's Exes

Making Music Together

Jen dated Counting Crowes frontman Adam Duriz in the early 1990s — the couple split in 1995.

More Than 'Friends'

Jen dated actor Tate Donovan from 1995 and 1998, when the two co-starred on “Friends.”

'Diagnosis' Dating

After splitting with Tate Donovan, Aniston is rumored to have dated actor Charlie Schlatter, best known for his role in “Diagnosis Murder.”

The Object of Her Affection

Romance on the set! Jennifer reportedly won Paul Rudd’s heart on the set of “The Object of My Affection” in 1998.

The One

America’s sweetheart began dating heartthrob Brad Pitt in 1998. The couple married in 2000, but divorced in 2005. Pitt is now with Angelina Jolie.

'Break-Up' Rebound

Shortly after Brad went public with Angelina in 2005, Jen began dating her “Break-Up” co-star Vince Vaughn. She split from the funnyman in December 2006.

Model Man

Aniston is rumored to have hooked up with model Paul Sculfor in 2007. After their fling, Sculfor began dating Cameron Diaz.

'Wonderland' Romance

Jen began quietly seeing singer John Mayer in May 2008. The couple went public at the 2009 Academy Awards, but split shortly after in March.

'Hangover' Hottie

Rumors swirled that Jennifer and Bradley Cooper went out together in 2009, but Coop denied the romance. Bradley has since started dating Renee Zellweger.

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